Applicability of the shell model for energy transfer /
In the cubic hexachloroelpasolite crystals Cs2NaSmxEuyGd1-x-yCl6 the emission from the 4G5/2 state of Sm3+ is strongly quenched by cross-relaxation and energy-transfer processes. At temperatures above 100 K the energy-transfer rate consists of non-resonant contributions due to electric dipole vibron...
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Jezik: | English |
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Journal of alloys and compounds |
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LEADER | 01619naa a2200241 ib4500 | ||
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001 | 96767489 | ||
003 | SI-MaCOB | ||
005 | 20190530000000.0 | ||
008 | 190530n1998||||sz a f||||||||| ||eng c | ||
024 | 7 | 1 | |a 10.1016/S0925-8388(98)00314-4 |2 doi |
041 | 0 | |a eng |b eng | |
080 | |a 54 |2 UDCMRF 2011 | ||
100 | 1 | |a Luxbacher, Thomas. |4 aut |0 (SI-MaCOB)122624099 | |
245 | 0 | 0 | |a Applicability of the shell model for energy transfer / |c Thomas Luxbacher, Harald P. Fritzer, Colin D. Flint. |
300 | |a str. 250-253 : |b Ilustr. | ||
504 | |a Bibliografija: str. 253. | ||
504 | |a Abstract. | ||
520 | |a In the cubic hexachloroelpasolite crystals Cs2NaSmxEuyGd1-x-yCl6 the emission from the 4G5/2 state of Sm3+ is strongly quenched by cross-relaxation and energy-transfer processes. At temperatures above 100 K the energy-transfer rate consists of non-resonant contributions due to electric dipole vibronic-electric dipole vibronic interaction and a near-resonant contribution where both the donor and acceptor transitions are magnetic-dipole allowed. The near-resonant energy-transfer rate is calculated and the small discrepancy between the theoretical and experimental values shows the applicability of the shell model for highly symmetric crystals. | ||
653 | 0 | |a energy transfer |a Hexachloroelpasolite crystals |a rare-earth ions |a shell model | |
700 | 1 | |a Fritzer, H. P. |4 aut |0 (SI-MaCOB)328090723 | |
700 | 1 | |a Flint, C. D. |4 aut |0 (SI-MaCOB)328093283 | |
773 | 0 | |t Journal of alloys and compounds |b [Print ed.] |d Lausanne : Elsevier Sequoia, 1991- |x 0925-8388 |g Vol. 275/277 (jul. 1998), str. 250-253 | |
040 | |a UKM |b slv |c SI-MaIIZ |e ppiak |