Modified freezing method for measuring the gas solubility along the solid-liquid-gas equilibrium line /
A new experimental technique for fast and efficient determinations of gas solubility in the liquid phase along the solid-liquid-gas equilibrium line of the binary system was designed and tested. The new technique based on the observation of pressure and temperature changes in the experimental system...
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| Main Authors: | , , , |
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| Format: | Book Chapter |
| Jezik: | English |
| Teme: | |
| Sorodne knjige/članki: | Vsebovano v:
Fluid phase equilibria |
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| LEADER | 02019naa a2200241 ib4500 | ||
|---|---|---|---|
| 001 | 7875862 | ||
| 003 | SI-MaCOB | ||
| 005 | 20040223000000.0 | ||
| 008 | 030506s2003 ne |||||||||||||| ||eng c | ||
| 040 | |a KTFMB |b slv |c SI-MaIIZ |d KTFMB |e ppiak | ||
| 080 | |a 66.02 | ||
| 245 | 1 | 0 | |a Modified freezing method for measuring the gas solubility along the solid-liquid-gas equilibrium line / |c Klementina Fukné-Kokot ... [et al.]. |
| 300 | |a str. 233-247. | ||
| 500 | |a Soavtorji: Mojca Škerget, Axel König, Željko Knez. | ||
| 504 | |a Bibliografija: str. 247. | ||
| 520 | |a A new experimental technique for fast and efficient determinations of gas solubility in the liquid phase along the solid-liquid-gas equilibrium line of the binary system was designed and tested. The new technique based on the observation of pressure and temperature changes in the experimental system while solid-liquid-gas equilibrium was established. Pressure-temperature-composition diagrams along the solid-liquid-gas equilibrium line for the binary systems biphenyl/CO2, vanillin/CO2, ethyl-o-vanillin/CO2 and benzoic acid/CO2 were determined up to 15.0 MPa and 423.2 K. These experimental data were plotted as (p-T) and (T-x) projections of three-phase solid-liquid-gas equilibrium line. Generally, it was observed that when the liquefaction temperature decreased along the three-phase solid-liquid-gas equilibrium line, the solubility of gas in the molten heavy component increased. | ||
| 653 | 0 | |a chemical processing |a PGSS micronisation |a gas solubility |a supercritical fluids |a CO2 |a S-L-G equilibrium |a organic compounds | |
| 653 | 0 | |a kemijska procesna tehnika |a PGSS mikronizacija |a topnost |a superkritični fluidi |a CO2 |a ravnotežje trdno-tekoče-plinasto |a organske spojine | |
| 700 | 1 | 2 | |a Fukne-Kokot, Klementina. |4 aut |
| 700 | 1 | 2 | |a Škerget, Mojca. |4 aut |
| 700 | 1 | 2 | |a König, Axel. |4 aut |
| 700 | 1 | 2 | |a Knez, Željko. |4 aut |
| 773 | 0 | |t Fluid phase equilibria |b [Print ed.] |d Amsterdam ; New York : Elsevier, 1977- |x 0378-3812 |g 205, issue 2 (2003), str. 233-247 | |